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Abstract We report production rates of H₂O and nine trace molecules (C₂H₆, CH₄, H₂CO, CH₃OH, HCN, NH₃, C₂H₂, OCS, and CO) in long-period comet C/2020 S3 (Erasmus) using the high-resolution, cross-dispersed infrared spectrograph (iSHELL) at the NASA Infrared Telescope Facility, on two pre-perihelion dates at heliocentric distancesR_h= 0.49 and 0.52 au. Our molecular abundances with respect to simultaneously or contemporaneously measured H₂O indicate that S3 is depleted in CH₃OH compared to its mean abundance relative to H₂O among the overall comet population (Oort Cloud comets and Jupiter-family comets combined), whereas the eight other measured species have near-average abundances relative to H₂O. In addition, compared to comets observed atR_h< 0.80 au at near-infrared wavelengths, S3 showed enhancement in the abundances of volatile species H₂CO, NH₃, and C₂H₂, indicating possible additional (distributed) sources in the coma for these volatile species. The spatial profiles of volatile species in S3 in different instrumental settings are dramatically different, which might suggest temporal variability in comet outgassing behavior between the nonsimultaneous measurements. The spatial distributions of simultaneously measured volatile species C₂H₆and CH₄are nearly symmetric and closely track each other, while those of CO and HCN co-measured with H₂O (using different instrument settings) are similar to each other and are asymmetric in the antisunward direction. 

Abstract Near-Earth asteroids (NEAs) are a key test bed for investigations into planet formation, asteroid dynamics, and planetary defense initiatives. These studies rely on understanding NEA sizes, albedo distributions, and regolith properties. Simple thermal models are a commonly used method for determining these properties; however, they have inherent limitations owing to the simplifying assumptions they make about asteroid shapes and properties. With the recent collapse of the Arecibo Telescope and a decrease of direct size measurements, as well as future facilities such as LSST and NEO Surveyor coming online soon, these models will play an increasingly important role in our knowledge of the NEA population. Therefore, it is key to understand the limits of these models. In this work we constrain the limitations of simple thermal models by comparing model results to more complex thermophysical models, radar data, and other existing analyses. Furthermore, we present a method for placing tighter constraints on inferred NEA properties using simple thermal models. These comparisons and constraints are explored using the NEA (285263) 1998 QE2 as a case study. We analyze QE2 with a simple thermal model and data from both the NASA IRTF SpeX instrument and NEOWISE mission. We determine an albedo between 0.05 and 0.10 and thermal inertia between 0 and 425J m −2 s −1/2 K −1 . We find that overall the simple thermal model is able to well constrain the properties of QE2; however, we find that model uncertainties can be influenced by topography, viewing geometry, and the wavelength range of data used. 

Abstract We present a comprehensive analysis of the chemical composition of the Jupiter-family comet and potential spacecraft target 46P/Wirtanen, in the near-IR wavelength range. We used iSHELL at the NASA Infrared Telescope Facility to observe the comet on 11 pre-, near-, and postperihelion dates in 2018 December and 2019 January and February during its historic apparition. We report rotational temperatures, production rates, and mixing ratios with respect to H 2 O and C 2 H 6 or 3 σ upper limits of the primary volatiles H 2 O, HCN, CH 4 , C 2 H 6 , CH 3 OH, H 2 CO, NH 3 , CO, C 2 H 2 , and HC 3 N. We also discuss the spatial outgassing of the primary volatiles, to understand their sources and the spatial associations between them. The spatial profiles of H 2 O in 46P/Wirtanen suggest the presence of extended H 2 O outgassing sources in the coma, similar to the EPOXI target comet 103P/Hartley 2. 46P/Wirtanen is among the few known hyperactive comets, and we note that its composition and outgassing behavior are similar to those of other hyperactive comets in many ways. We note that the analyzed parent volatiles showed different variations (relative mixing ratios) during the apparition. We compared the chemical composition of 46P/Wirtanen with the mean abundances in Jupiter-family comets and the comet population as measured with ground-based near-IR facilities to date. The molecular abundances in 46P/Wirtanen suggest that although they were changing, the variations were small compared to the range in the comet population, with CH 3 OH showing notably more variation as compared to the other molecules. 

Abstract High-resolution infrared spectra of comet C/2014 Q2 Lovejoy were acquired with NIRSPEC at the W. M. Keck Observatory on two post-perihelion dates (UT 2015 February 2 and 3). H 2 O was measured simultaneously with CO, CH 3 OH, H 2 CO, CH 4 , C 2 H 6 , C 2 H 4 , C 2 H 2 , HCN, and NH 3 on both dates, and rotational temperatures, production rates, relative abundances, H 2 O ortho-to-para ratios, and spatial distributions in the coma were determined. The first detection of C 2 H 4 in a comet from ground-based observations is reported. Abundances relative to H 2 O for all species were found to be in the typical range compared with values for other comets in the overall population to date. There is evidence of variability in rotational temperatures and production rates on timescales that are small compared with the rotational period of the comet. Spatial distributions of volatiles in the coma suggest complex outgassing behavior. CH 3 OH, HCN, C 2 H 6 , and CH 4 spatial distributions in the coma are consistent with direct release from associated ices in the nucleus and are peaked in a more sunward direction compared with co-measured dust. H 2 O spatial profiles are clearly distinct from these other four species, likely due to a sizable coma contribution from icy grain sublimation. Spatial distributions for C 2 H 2 , H 2 CO, and NH 3 suggest substantial contributions from extended coma sources, providing further evidence for distinct origins and associations for these species in comets. CO shows a different spatial distribution compared with other volatiles, consistent with jet activity from discrete nucleus ice sources.